A Thorny Problem? Spinodal Decomposition in Polymer Blends
نویسندگان
چکیده
منابع مشابه
Interdiffusion and Spinodal Decomposition in Electrically Conducting Polymer Blends
The impact of phase morphology in electrically conducting polymer composites has become essential for the efficiency of the various functional applications, in which the continuity of the electroactive paths in multicomponent systems is essential. For instance in bulk heterojunction organic solar cells, where the light-induced electron transfer through photon absorption creating excitons (elect...
متن کاملNONLINEAR KINETICS OF SPINODAL DECOMPOSITION, AND DISSOLUTION OF INHOMOGENElTIES FORMED BY SPINODAL DECOMPOSITION IN POLYMER BLENDS
Nonlinear kinetics of both spinodal decomposition at early stages, and the dissolution of homogeneities formed during spinodal decomposition,is studied. Variation of the scattering intensity during a complete cycle consisting of a step temperature change from T i in the one-phase. region to T2 in the two-phase region, a period of spinodal decomposition followed by a temperature drop from T2 bac...
متن کاملShear-induced shift of spinodal line in entangled polymer blends.
We study the shear-flow effects on phase separation of entangled polymer blends by incorporating into the chemical potential a nonequilibrium contribution due to the flow. The results are compared with those of a previous analysis by other authors which did not modify the chemical potential but used a different assumption for the stress tensor of the blend.
متن کاملSpinodal decomposition in a model colloid-polymer mixture in microgravity.
We study phase separation in a deeply quenched colloid-polymer mixture in microgravity on the International Space Station using small-angle light scattering and direct imaging. We observe a clear crossover from early-stage spinodal decomposition to late-stage, interfacial-tension-driven coarsening. Data acquired over 5 orders of magnitude in time show more than 3 orders of magnitude increase in...
متن کاملSpinodal decomposition of a confined colloid-polymer system.
We study the demixing via spinodal decomposition of a fluid-fluid phase separating colloid-polymer mixture confined between parallel plates, where one of the phases completely wets both walls. Using confocal scanning laser microscopy, we are able to obtain real space images, both parallel and perpendicular to the cell walls. We observe three distinct morphologies: the formation of a bicontinuou...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Macromolecules
سال: 2020
ISSN: 0024-9297,1520-5835
DOI: 10.1021/acs.macromol.0c00581